# Supplementary Material (ESI) for Organic & Biomolecular Chemistry
# This journal is © The Royal Society of Chemistry 2003

data_global

_journal_coden_Cambridge         177

loop_
_publ_author_name
'Andreas Schmidt'
'Abbas Gholipour Shilabin'
'Martin Nieger'

_publ_contact_author_name        'Dr Andreas Schmidt'
_publ_contact_author_address     
;
Institute of Organic Chemistry
Technical University of Clausthal
Leibnizstrasse 6
Clausthal-Zellerfeld
D-38678
GERMANY
;

_publ_contact_author_email       SCHMIDT@IOC.TU-CLAUSTHAL.DE

_publ_requested_journal          'Organic & Biomolecular Chemistry'

_publ_section_title              
;
On Benzo[b][1,4]diazepinium-olates, -thiolates and -carboxylates as
Anti-Huckel Mesomeric Betaines
;
#==============================================================================

data_schm13_AB-2
_database_code_CSD               216056

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
7-Carboxy-2,4-dimethyl-5H-benzo[b][1,4]diazepin-ium picrate
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         '(C12 H13 N2 O2)+ (C6 H2 N3 O7)- MeOH'
_chemical_formula_sum            'C19 H19 N5 O10'
_chemical_formula_weight         477.39

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1
_symmetry_Int_Tables_number      2

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.8117(2)
_cell_length_b                   11.0726(2)
_cell_length_c                   11.2477(3)
_cell_angle_alpha                79.339(1)
_cell_angle_beta                 73.059(1)
_cell_angle_gamma                86.946(1)
_cell_volume                     1031.68(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    123(2)
_cell_measurement_reflns_used    4569
_cell_measurement_theta_min      1
_cell_measurement_theta_max      27.5

_exptl_crystal_description       plates
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      none
_exptl_crystal_density_diffrn    1.537
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             496
_exptl_absorpt_coefficient_mu    0.127
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
dx = 40 mm, 60 sec./deg., 2 deg., 9 sets, 410 frames, mos.= 0.649(2) deg.
;

_diffrn_ambient_temperature      123(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'rotation in phi and omega, 2 deg,'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        none
_diffrn_reflns_number            17842
_diffrn_reflns_av_R_equivalents  0.0368
_diffrn_reflns_av_sigmaI/netI    0.0285
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.91
_diffrn_reflns_theta_max         25.00
_reflns_number_total             3648
_reflns_number_gt                3035
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       Collect
_computing_cell_refinement       DENZO-SMN
_computing_data_reduction        DENZO-SMN
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    SHELXTL-NT
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'

_refine_special_details          
;
Refinement of F² against ALL reflections.  The weighted R-factor wR and
goodness of fit S are based on F², conventional R-factors R are based
on F, with F set to zero for negative F². The threshold expression of
F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement.  R-factors based
on F² are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0667P)²+0.4235P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3648
_refine_ls_number_parameters     322
_refine_ls_number_restraints     4
_refine_ls_R_factor_all          0.0519
_refine_ls_R_factor_gt           0.0431
_refine_ls_wR_factor_ref         0.1218
_refine_ls_wR_factor_gt          0.1165
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_restrained_S_all      1.074
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.69336(18) 0.65468(14) 1.00103(15) 0.0226(4) Uani 1 1 d D . .
H1N H 0.712(2) 0.6798(19) 1.0634(17) 0.027 Uiso 1 1 d D . .
C2 C 0.6341(2) 0.73837(16) 0.92494(17) 0.0219(4) Uani 1 1 d . . .
C3 C 0.5910(2) 0.72125(17) 0.82031(18) 0.0256(4) Uani 1 1 d . . .
H3 H 0.5580 0.7936 0.7744 0.031 Uiso 1 1 calc R . .
C4 C 0.5884(2) 0.61467(16) 0.77161(17) 0.0211(4) Uani 1 1 d . . .
N5 N 0.63665(17) 0.50389(14) 0.81290(15) 0.0220(3) Uani 1 1 d D . .
H5N H 0.625(2) 0.4477(17) 0.7738(19) 0.026 Uiso 1 1 d D . .
C6 C 0.7158(2) 0.46251(16) 0.90699(16) 0.0195(4) Uani 1 1 d . . .
C7 C 0.7730(2) 0.34344(16) 0.91057(16) 0.0206(4) Uani 1 1 d . . .
H7 H 0.7588 0.2975 0.8512 0.025 Uiso 1 1 calc R . .
C8 C 0.8508(2) 0.28875(16) 0.99858(17) 0.0213(4) Uani 1 1 d . . .
C9 C 0.8678(2) 0.35438(16) 1.08756(17) 0.0227(4) Uani 1 1 d . . .
H9 H 0.9168 0.3178 1.1504 0.027 Uiso 1 1 calc R . .
C10 C 0.8123(2) 0.47415(17) 1.08362(17) 0.0218(4) Uani 1 1 d . . .
H10 H 0.8252 0.5192 1.1442 0.026 Uiso 1 1 calc R . .
C11 C 0.7386(2) 0.53056(16) 0.99454(16) 0.0192(4) Uani 1 1 d . . .
C12 C 0.9172(2) 0.16247(16) 0.99662(17) 0.0223(4) Uani 1 1 d . . .
O1 O 0.88962(17) 0.10681(12) 0.91274(13) 0.0295(3) Uani 1 1 d D . .
H1O H 0.930(3) 0.0326(17) 0.917(2) 0.044 Uiso 1 1 d D . .
O2 O 0.99385(17) 0.11785(12) 1.07021(13) 0.0334(4) Uani 1 1 d . . .
C13 C 0.6091(2) 0.86242(17) 0.9615(2) 0.0293(4) Uani 1 1 d . . .
H13A H 0.4958 0.8824 0.9826 0.044 Uiso 1 1 calc R . .
H13B H 0.6679 0.9239 0.8909 0.044 Uiso 1 1 calc R . .
H13C H 0.6474 0.8624 1.0351 0.044 Uiso 1 1 calc R . .
C14 C 0.5222(2) 0.62325(17) 0.66138(18) 0.0272(4) Uani 1 1 d . . .
H14A H 0.5795 0.5665 0.6064 0.041 Uiso 1 1 calc R . .
H14B H 0.5346 0.7074 0.6136 0.041 Uiso 1 1 calc R . .
H14C H 0.4094 0.6015 0.6922 0.041 Uiso 1 1 calc R . .
C1' C 0.2145(2) 0.22624(17) 0.68158(17) 0.0227(4) Uani 1 1 d . . .
C2' C 0.1254(2) 0.30147(16) 0.60631(17) 0.0215(4) Uani 1 1 d . . .
C3' C 0.0800(2) 0.26806(17) 0.51056(17) 0.0235(4) Uani 1 1 d . . .
H3' H 0.0161 0.3209 0.4683 0.028 Uiso 1 1 calc R . .
C4' C 0.1297(2) 0.15501(17) 0.47688(17) 0.0235(4) Uani 1 1 d . . .
C5' C 0.2180(2) 0.07653(17) 0.54016(18) 0.0247(4) Uani 1 1 d . . .
H5' H 0.2531 0.0002 0.5147 0.030 Uiso 1 1 calc R . .
C6' C 0.2554(2) 0.10908(17) 0.64094(18) 0.0240(4) Uani 1 1 d . . .
O1' O 0.25085(16) 0.26135(12) 0.77049(12) 0.0282(3) Uani 1 1 d . . .
N2' N 0.0811(2) 0.42547(15) 0.63025(14) 0.0286(4) Uani 1 1 d . . .
O21' O -0.05665(18) 0.45826(13) 0.63717(13) 0.0373(4) Uani 1 1 d . . .
O22' O 0.1833(2) 0.49179(13) 0.63863(15) 0.0446(4) Uani 1 1 d . . .
N4' N 0.0835(2) 0.11913(15) 0.37492(16) 0.0312(4) Uani 1 1 d . . .
O41' O 0.13966(18) 0.02428(13) 0.33735(14) 0.0372(4) Uani 1 1 d . . .
O42' O -0.0132(2) 0.18425(15) 0.33261(16) 0.0533(5) Uani 1 1 d . . .
N6' N 0.3419(2) 0.01713(15) 0.70550(16) 0.0305(4) Uani 1 1 d . . .
O61' O 0.3379(2) 0.02060(15) 0.81423(16) 0.0554(5) Uani 1 1 d . . .
O62' O 0.4124(2) -0.06344(17) 0.65045(17) 0.0633(6) Uani 1 1 d . . .
O1E O 0.56690(18) 0.31250(15) 0.70665(17) 0.0457(4) Uani 1 1 d D . .
H1E H 0.470(2) 0.300(3) 0.724(3) 0.068 Uiso 1 1 d D . .
C1E C 0.6578(3) 0.2311(3) 0.6353(3) 0.0669(9) Uani 1 1 d . . .
H1E1 H 0.7703 0.2447 0.6245 0.100 Uiso 1 1 calc R . .
H1E2 H 0.6385 0.2443 0.5523 0.100 Uiso 1 1 calc R . .
H1E3 H 0.6288 0.1466 0.6784 0.100 Uiso 1 1 calc R . .


_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix.  The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry.  An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C2 1.334(2) . ?
N1 C11 1.419(2) . ?
N1 H1N 0.861(15) . ?
C2 C3 1.384(3) . ?
C2 C13 1.493(2) . ?
C3 C4 1.394(3) . ?
C3 H3 0.9500 . ?
C4 N5 1.323(2) . ?
C4 C14 1.503(2) . ?
N5 C6 1.426(2) . ?
N5 H5N 0.851(15) . ?
C6 C7 1.384(2) . ?
C6 C11 1.409(2) . ?
C7 C8 1.395(3) . ?
C7 H7 0.9500 . ?
C8 C9 1.386(2) . ?
C8 C12 1.488(2) . ?
C9 C10 1.386(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.385(3) . ?
C10 H10 0.9500 . ?
C12 O2 1.235(2) . ?
C12 O1 1.301(2) . ?
O1 H1O 0.878(16) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C1' O1' 1.264(2) . ?
C1' C2' 1.443(3) . ?
C1' C6' 1.447(3) . ?
C2' C3' 1.368(3) . ?
C2' N2' 1.459(2) . ?
C3' C4' 1.387(3) . ?
C3' H3' 0.9500 . ?
C4' C5' 1.374(3) . ?
C4' N4' 1.448(2) . ?
C5' C6' 1.380(3) . ?
C5' H5' 0.9500 . ?
C6' N6' 1.453(2) . ?
N2' O22' 1.227(2) . ?
N2' O21' 1.233(2) . ?
N4' O41' 1.230(2) . ?
N4' O42' 1.232(2) . ?
N6' O62' 1.219(2) . ?
N6' O61' 1.221(2) . ?
O1E C1E 1.384(3) . ?
O1E H1E 0.836(17) . ?
C1E H1E1 0.9800 . ?
C1E H1E2 0.9800 . ?
C1E H1E3 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 N1 C11 131.11(15) . . ?
C2 N1 H1N 115.8(14) . . ?
C11 N1 H1N 113.0(14) . . ?
N1 C2 C3 127.28(16) . . ?
N1 C2 C13 114.70(16) . . ?
C3 C2 C13 118.00(16) . . ?
C2 C3 C4 130.23(17) . . ?
C2 C3 H3 114.9 . . ?
C4 C3 H3 114.9 . . ?
N5 C4 C3 127.01(17) . . ?
N5 C4 C14 115.10(15) . . ?
C3 C4 C14 117.89(16) . . ?
C4 N5 C6 131.11(15) . . ?
C4 N5 H5N 115.7(14) . . ?
C6 N5 H5N 113.0(14) . . ?
C7 C6 C11 118.61(16) . . ?
C7 C6 N5 115.16(15) . . ?
C11 C6 N5 126.23(16) . . ?
C6 C7 C8 122.13(16) . . ?
C6 C7 H7 118.9 . . ?
C8 C7 H7 118.9 . . ?
C9 C8 C7 119.08(16) . . ?
C9 C8 C12 120.00(16) . . ?
C7 C8 C12 120.92(16) . . ?
C8 C9 C10 119.04(17) . . ?
C8 C9 H9 120.5 . . ?
C10 C9 H9 120.5 . . ?
C11 C10 C9 122.38(16) . . ?
C11 C10 H10 118.8 . . ?
C9 C10 H10 118.8 . . ?
C10 C11 C6 118.70(16) . . ?
C10 C11 N1 115.28(15) . . ?
C6 C11 N1 126.02(16) . . ?
O2 C12 O1 124.43(16) . . ?
O2 C12 C8 120.29(15) . . ?
O1 C12 C8 115.27(15) . . ?
C12 O1 H1O 111.1(16) . . ?
C2 C13 H13A 109.5 . . ?
C2 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C2 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C4 C14 H14A 109.5 . . ?
C4 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C4 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
O1' C1' C2' 122.89(17) . . ?
O1' C1' C6' 125.84(17) . . ?
C2' C1' C6' 111.27(16) . . ?
C3' C2' C1' 125.72(16) . . ?
C3' C2' N2' 115.64(16) . . ?
C1' C2' N2' 118.63(15) . . ?
C2' C3' C4' 118.18(17) . . ?
C2' C3' H3' 120.9 . . ?
C4' C3' H3' 120.9 . . ?
C5' C4' C3' 121.22(17) . . ?
C5' C4' N4' 120.08(16) . . ?
C3' C4' N4' 118.68(16) . . ?
C4' C5' C6' 119.72(17) . . ?
C4' C5' H5' 120.1 . . ?
C6' C5' H5' 120.1 . . ?
C5' C6' C1' 123.75(17) . . ?
C5' C6' N6' 115.42(16) . . ?
C1' C6' N6' 120.83(16) . . ?
O22' N2' O21' 123.99(17) . . ?
O22' N2' C2' 118.45(17) . . ?
O21' N2' C2' 117.53(16) . . ?
O41' N4' O42' 123.61(16) . . ?
O41' N4' C4' 118.57(16) . . ?
O42' N4' C4' 117.80(16) . . ?
O62' N6' O61' 121.99(17) . . ?
O62' N6' C6' 118.79(16) . . ?
O61' N6' C6' 119.18(16) . . ?
C1E O1E H1E 113(2) . . ?
O1E C1E H1E1 109.5 . . ?
O1E C1E H1E2 109.5 . . ?
H1E1 C1E H1E2 109.5 . . ?
O1E C1E H1E3 109.5 . . ?
H1E1 C1E H1E3 109.5 . . ?
H1E2 C1E H1E3 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 N1 C2 C3 4.6(3) . . . . ?
C11 N1 C2 C13 -177.08(18) . . . . ?
N1 C2 C3 C4 4.3(3) . . . . ?
C13 C2 C3 C4 -173.96(19) . . . . ?
C2 C3 C4 N5 -4.1(3) . . . . ?
C2 C3 C4 C14 174.98(19) . . . . ?
C3 C4 N5 C6 -6.4(3) . . . . ?
C14 C4 N5 C6 174.49(17) . . . . ?
C4 N5 C6 C7 -169.23(18) . . . . ?
C4 N5 C6 C11 11.3(3) . . . . ?
C11 C6 C7 C8 0.6(3) . . . . ?
N5 C6 C7 C8 -178.91(16) . . . . ?
C6 C7 C8 C9 1.8(3) . . . . ?
C6 C7 C8 C12 -177.33(16) . . . . ?
C7 C8 C9 C10 -2.4(3) . . . . ?
C12 C8 C9 C10 176.71(16) . . . . ?
C8 C9 C10 C11 0.7(3) . . . . ?
C9 C10 C11 C6 1.7(3) . . . . ?
C9 C10 C11 N1 -178.07(16) . . . . ?
C7 C6 C11 C10 -2.3(2) . . . . ?
N5 C6 C11 C10 177.16(16) . . . . ?
C7 C6 C11 N1 177.43(16) . . . . ?
N5 C6 C11 N1 -3.1(3) . . . . ?
C2 N1 C11 C10 173.30(18) . . . . ?
C2 N1 C11 C6 -6.5(3) . . . . ?
C9 C8 C12 O2 -3.4(3) . . . . ?
C7 C8 C12 O2 175.74(17) . . . . ?
C9 C8 C12 O1 177.44(16) . . . . ?
C7 C8 C12 O1 -3.5(3) . . . . ?
O1' C1' C2' C3' -178.75(18) . . . . ?
C6' C1' C2' C3' 1.6(3) . . . . ?
O1' C1' C2' N2' 2.7(3) . . . . ?
C6' C1' C2' N2' -176.98(15) . . . . ?
C1' C2' C3' C4' -3.7(3) . . . . ?
N2' C2' C3' C4' 174.97(16) . . . . ?
C2' C3' C4' C5' 2.0(3) . . . . ?
C2' C3' C4' N4' -179.45(16) . . . . ?
C3' C4' C5' C6' 1.4(3) . . . . ?
N4' C4' C5' C6' -177.08(17) . . . . ?
C4' C5' C6' C1' -3.6(3) . . . . ?
C4' C5' C6' N6' 176.92(16) . . . . ?
O1' C1' C6' C5' -177.54(18) . . . . ?
C2' C1' C6' C5' 2.1(3) . . . . ?
O1' C1' C6' N6' 1.9(3) . . . . ?
C2' C1' C6' N6' -178.46(16) . . . . ?
C3' C2' N2' O22' -130.71(18) . . . . ?
C1' C2' N2' O22' 48.0(2) . . . . ?
C3' C2' N2' O21' 47.2(2) . . . . ?
C1' C2' N2' O21' -134.05(17) . . . . ?
C5' C4' N4' O41' -8.1(3) . . . . ?
C3' C4' N4' O41' 173.34(17) . . . . ?
C5' C4' N4' O42' 170.17(19) . . . . ?
C3' C4' N4' O42' -8.4(3) . . . . ?
C5' C6' N6' O62' 19.9(3) . . . . ?
C1' C6' N6' O62' -159.6(2) . . . . ?
C5' C6' N6' O61' -157.92(19) . . . . ?
C1' C6' N6' O61' 22.6(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1N O1' 0.861(15) 2.202(16) 3.0626(19) 176.9(19) 2_667
N5 H5N O1E 0.851(15) 1.950(16) 2.793(2) 170(2) .
O1 H1O O2 0.878(16) 1.758(17) 2.6354(18) 178(3) 2_757
O1E H1E O1' 0.836(17) 1.894(18) 2.728(2) 176(3) .

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.673
_refine_diff_density_min         -0.413
_refine_diff_density_rms         0.054

#==============================================================================
#_eof # End of Crystallographic Information File


